Charging Ring Spectroscopy and Defect Identification in Graphene/Boron Nitride Through Scanning Tunneling Microscopy

ORAL

Abstract

Tip-induced ionization of defects in semiconductors and surface adatoms is known to cause ring-like structures in scanning tunneling spectroscopy (STS). We report the observation and investigation of charging ring structures in bulk insulating hexagonal boron nitride (BN) capped by a monolayer of graphene. These rings provide quantitative information on the energy levels of the ionizable BN defects, providing insight into their chemical identities. This new technique suggests exciting possibilities for quantitative spectroscopic studies of defects in other insulating systems.

Authors

  • Juwon Lee

    • Univ of California - Berkeley
  • Dillon Wong

    • Univ of California - Berkeley
  • Jairo Valesco

    • Univ of California - Berkeley
  • Long Ju

    • Univ of California - Berkeley
  • Salman Kahn

    • Univ of California - Berkeley
  • Hsinzon Tsai

    • Univ of California - Berkeley
  • Chad Germany

    • Univ of California - Berkeley
  • Takashi Taniguchi

    • National Institute for Material Science
  • Kenji Watanabe

    • National Institute for Material Science
  • Alex Zettl

    • Univ of California - Berkeley
  • Feng Wang

    • Univ of California - Berkeley
  • Michael Crommie

    • Univ of California - Berkeley