High Resolution Imaging of Graphene on SiC by Contact Resonance AFM: Experiment and Theory

ORAL

Abstract

Contact resonance atomic force microscopy (CR-AFM)[1] is a powerful tool for mapping differences of the mechanical properties of layered, 2D materials. The deconvolution of stiffness contributions arising from the different layers is, however, difficult. Here, density functional theory (DFT) calculations can help interpret experimental results. Few-layer graphene (FLG; mono-, bi-, or trilayer thickness) on silicon carbide (SiC) exhibits very clean and distinct surfaces and yields high-contrast CR-AFM images. To interpret the contributions from surface areas with different layer thickness and structure we use DFT to calculate atomic displacements for forces acting on FLG on SiC using the $\sqrt{3} \times \sqrt{3}$ and the $6\sqrt{3} \times 6\sqrt{3}$ structure models. Based on these displacements we calculate an effective modulus using a simple spring model. The resulting moduli can then be compared with those extracted from experimental CR-AFM measurements of FLG on SiC.\\[4pt] [1] Yamanaka, K and Nakano, S, Applied Physics A: Materials Science {\&} Processing, S313--S317, (1998)

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Authors

  • Qing Tu

    • Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC, USA

  • Bjoern Lange

    • Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC, USA

  • Joao Marcelo Lopes

    • Paul-Drude-Institut f\"ur Festk\"orperelektronik, Hausvogteiplatz 5-7, D-10117 Berlin, Germany

  • Stefan Zauscher

    • Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC, USA

  • Volker Blum

    • Duke University
    • Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC, USA
    • Department of Mechanical Engineering and Material Science, Duke University, Durham, NC, USA
    • Fritz-Haber-Institut der MPG, Berlin, DE; Duke University, Durham, NC, USA