Origins of Persistent Photoconductivity in Highly Mismatched Semiconductor Alloys
ORAL
Abstract
Persistent photoconductivity (PPC) is a nonequilibrium phenomenon in which an illumination-induced increase in conductivity of a semiconductor persists following the termination of illumination. The PPC effect has been explained in terms of the large-lattice-relaxation (LLR) model, in which photoexcited carriers are unable to relax to equilibrium due to an energy barrier between shallow donor and deep donor complex (DX) center configurations. To date, an experimental identification of atomistic configurations in support of a model for the PPC effect has yet to be reported. Here, we examine the origins of the PPC effect in GaAsN alloy films, providing the first direct correlation between the concentration of interstitials and the strength of the PPC effect. Thus, the PPC effect in GaAsN is attributed to a change in the bond orientation or a shift in the center of mass of either N-N or N-As pairs. Similar investigations of GaAsBi alloy films will be discussed.
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