On plasma based species deposition at a Pyrex surface studied by post plasma N$_{x}$O$_{y}$ conversion

ORAL

Abstract

The deposition of atomic species at the inner surface of a Pyrex tube RF plasma reactor was studied by measuring the time dependent conversion of N$_{x}$O$_{y}$ in a post plasma experiment. First the inner surface of the tube was treated by a capacitively coupled RF plasma with different precursors. Then following the plasma phase, after evacuation a gas mixture (1{\%} N$_{x}$O$_{y}$ in N$_{2})$ was filled into the tube. The time evolutions of NO, NO$_{2}$ and N$_{2}$O were measured using a 3 laser QCLAS system. It was found, that only after the usage of oxygen containing precursor gases NO was oxidised into NO$_{2}$. The N$_{2}$O concentration did not show any changes over time. A modelling approach showed good agreement with the experiment.

Authors

  • Juergen Roepcke

    • INP-Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald
    • INP Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald, Germany
    • INP Greifswald, Germany
  • M. Huebner

    • INP-Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald, Germany
    • INP Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald, Germany
  • Daniil Marinov

    • LPP, Ecole Polytechnique, UPMC, Universite Paris Sud-11, CNRS, Palaiseau, France
  • Olivier Guaitella

    • LPP, Ecole Polytechnique, UPMC, Universit\'e Paris Sud-11, CNRS, Palaiseau, France
    • LPP, Ecole Polytechnique, UPMC, Universite Paris Sud-11, CNRS, Palaiseau, France
  • Antoine Rousseau

    • Ecole Polytechnique
    • LPP, Ecole Polytechnique, UPMC, Universite Paris Sud-11, CNRS, Palaiseau, France
    • Laboratoire de Physique des Plasmas
    • LPP
    • LPP, Ecole Polytechnique, UPMC, Universit\'e Paris Sud-11, CNRS, Palaiseau, France
  • Carlos D. Pintassilgo

    • IPFN-Laboratorio Associado, IST, 1049-001 Lisboa, Portugal
    • IPFN - Laboratorio Associado, IST, Lisboa, Portugal
  • Vasco Guerra

    • IPFN-LA, Instituto Superior Tecnico, 1049-001 Lisboa, Portugal
    • Instituto de Plasmas e Fusao Nuclear - Laboratorio Associado, Instituto Superior Tecnico, 1049-001 Lisboa, Portugal
    • Instituto de Plasmas e Fus\~ao Nuclear - Laboratorio Associado, Instituto Superior Tecnico, 1049-001 Lisboa, Portugal
    • IPFN - Laboratorio Associado, IST, Lisboa, Portugal