Magnetoelastic dynamics of the ``spin Jahn-Teller'' transition in CoTi<sub>2</sub>O<sub>5</sub>

ORAL  · Invited

Abstract

CoTi2O5 has the paradox that the low temperature static and spatially long-range magnetic order is incompatible with the crystal structure owing to a mirror plane that exactly frustrates magnetic interactions. However, despite no observable structural distortion with diffraction, CoTi2O5 does magnetically order below TN~25 K with the breaking of spin ground state degeneracy proposed to be a realization of the spin Jahn-Teller effect in analogy to the celebrated orbital Jahn-Teller transition. We apply neutron and Raman spectroscopy to study the dynamics of this transition in CoTi2O5. We find anomalous acoustics associated with a symmetry breaking strain that characterizes the spin Jahn-Teller transition. Crucially, the energy of this phonon coincides with the energy scale of the magnetic excitations, and has the same symmetry of an optic mode, observed with Raman spectroscopy, with an atypical temperature dependence. Taken together, we propose that the energetics of the spin Jahn-Teller effect in CoTi2O5 are related to cooperative magnetoelastic fluctuations as opposed to conventional soft critical dynamics which typically drive large measurable static displacements.

*We would like to thank the EPSRC and the STFC for funding this work.

Presenters

  • Chris Stock

    • University of Edinburgh

Authors

  • Chris Stock

    • University of Edinburgh
  • Roger D Johnson

    • University College London
  • K. Guratinder

    • University of Edinburgh
  • Dharmalingam Prabhakaran

    • Oxford Physics
    • Oxford University
  • Tom Fennell

    • Paul Scherrer Institut
  • Karin Schmalzl

    • ILL
  • Travis J Williams

    • Oak Ridge National Laboratory
  • Sean R Giblin

    • Cardiff Univ of Wales
    • Cardiff University
  • Stephen Blundell

    • University of Oxford
  • Sergey V Streltsov

    • Institute of Metal Physics
  • Leonid S Taran

    • M. N. Mikheev Institute of Metal Physics
    • Ural Branch of Russian Academy of Sciences