(symp) X-ray diffraction study of laser-shocked forsterite (Mg$_{\mathrm{2}}$SiO$_{\mathrm{4}})$ from 20-130 GPa

POSTER

Abstract

Forsterite, Mg$_{\mathrm{2}}$SiO$_{\mathrm{4}}$, is of fundamental importance for geophysics as the magnesium end-member of the olivine (Mg,Fe)$_{\mathrm{2}}$SiO$_{\mathrm{4}}$ solid solution. Interest in the dynamic behavior of olivine is motivated by understanding the nature of shock-induced phase transition in silicates during hypervelocity collisions. While it is known from gas-gun experiments that olivine transitions to a high-pressure phase under shock compression, there are few constraints on the structure of the high-pressure phase. We have carried out an \textit{in situ} x-ray diffraction study of laser-shocked polycrystalline and single-crystal (a-, b-, and c- orientation) forsterite from 20 GPa to 130 GPa using the Matter in Extreme Conditions beamline of the Linac Coherent Light Source. Consistent with earlier gas-gun experiments (Newman et al., 2018), we observe forsterite III, a metastable structure of Mg$_{\mathrm{2}}$SiO$_{\mathrm{4}}$, from 50 to 110 GPa. When compressed above 110 GPa, forsterite III undergoes amorphization. Our results show a reversion to the ambient forsterite structure during release over nanosecond timescales.

*Work supported by DOE/FES

Authors

  • Donghoon Kim

    • Princeton University
    • Princeton
  • E. Berryman

    • Princeton
    • Princeton University
  • Sirus Han

    • Princeton University
    • Princeton
  • Thomas Duffy

    • Princeton University
    • Princeton
  • S. Tracy

    • Carnegie Institution
    • Carnegie Institution for Science
    • Geophysical Laboratory, Carnegie Institution of Washington
  • A. Gleason

    • Stanford
    • SLAC
    • SLAC National Accelerator Laboratory
  • C. Blome

    • Los Alamos National Laboratory
    • LANL
  • K. Appel

    • European XFEL
  • M. Schoelmerich

    • European XFEL
  • V. Prakapenka

    • Uni. of Chicago
  • H. Lee

    • SLAC
  • B. Nagler

    • SLAC
  • R. Smith

    • LLNL
  • M. Akin

    • LLNL
  • J. Eggert

    • LLNL
  • P. Asimow

    • Caltech