X-ray diffraction study of ramp-compressed Fe and MgO

ORAL

Abstract

The study of Fe and MgO under extreme conditions of pressure and temperature is of great relevance for a variety of fields ranging from basic science and high-pressure condensed matter to geophysics and planetary science. We used laser-driven ramp-compression to achieve 5 and 9 Mbar in Fe and MgO respectively and the structural evolution and transformations were documented by in-situ x-ray diffraction. Velocity interferometry was used to infer the pressure. We found that the hexagonal close-packed (hcp) structure of iron remains stable up to 5 Mbar with no significant change in the c/a ratio. A new phase of MgO was observed above 6 Mbar and it is consistent with the CsCl (B2) structure. The new polymorph remains stable up to 9 Mbar, the highest pressure reached in our experiments.

*This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Authors

  • Federica Coppari

    • Lawrence Livermore National Laboratory
    • LLNL
  • Raymond Smith

    • Lawrence Livermore National Laboratory
    • LLNL
  • Jon H. Eggert

    • LLNL
    • Lawrence Livermore National Laboratory
  • Ryan Rygg

    • LLNL
    • Lawrence Livermore National Laboratory
  • Amy Lazicki

    • Lawrence Livermore National Laboratory
  • James Hawreliak

    • LLNL
    • Lawrence Livermore National Laboratory
  • Damien Hicks

    • Lawrence Livermore National Laboratory
  • Jue Wang

    • Princeton University
  • Thomas Duffy

    • Princeton University
  • Gilbert Collins

    • LLNL
    • Lawrence Livermore National Laboratory
    • Lawrence Livermore National Lab