Nonmonotonic conductivity change of C60 fullerene crystals under dynamic compression up to 300 kbar

ORAL

Abstract

In the present work the conductivity of fullerene C$_{60}$ crystals has been measured under smooth shock wave quasi-isentropic loading conditions up to 30 GPa at initial temperature T=293 K. Not monotone behavior of conductivity has been revealed under compression of crystal with pressure increasing: -at first conductivity grows by many orders then it falls very fast. Conductivity increasing is explained by decreasing of bandgap of C$_{60}$ under compression whereas conductivity decreasing can be explained on the assumption that the energy barrier of polymerization of C$_{60}$ reduces with pressure increasing approximately in the same measure as band-gap energy. Research is financially supported by the Russian foundation for basic research, the grant N 03-02-16322, the grant of the President of Russia NS 1938.2003.2, and program of basic researches of the Russian Academy of Science ``Thermophysics and mechanics of processes at high energy densities.''

Authors

  • Vladimir V. Avdonin

  • V.I. Postnov

  • D.V. Shakhray

  • K.L. Kagan

  • A.F. Shestakov

  • V.E. Fortov

    • Institute of Chemical Physics, Moscow
    • Institute for High Energy Densities of Russian Academy of Sciences (IHED RAS)
    • Institute for High Energy Density Physics RAS
    • IPCP RAS
    • Institute of Problem of Chemical Physics RAS
  • V.V. Kveder

  • R.K. Nikolaev

  • N.S. Sidorov

  • Y.A. Ossipyan

    • Institute of Solid State Physics RAS