Bringing the SWIR to Silicon with Upconversion Devices

POSTER

Abstract

Infrared imaging, encompassing a spectrum of applications from healthcare to autonomous vehicles, has emphasized the need for advancing Near Infrared (NIR) and Short Wave Infrared (SWIR) detection capabilities. The potential to transform NIR and SWIR photons into detectable NIR photons via upconversion, compatible with prevalent silicon-based cameras, poses a formidable challenge to the current InGaAs sensor-dominated market. This dominance is characterized by intricate fabrication methodologies and heightened device costs, constraining the scalability of imaging solutions in this domain. Our research introduces a paradigm shift through the deployment of solid-state triplet-triplet annihilation upconversion via a charge-transfer state sensitization process. We present a pioneering single-step solution-processed deposition of a bulk heterojunction upconversion film employing organic semiconductors. Demonstrations across varied substrates, including glass and flexible mediums, underscore the versatility and potential of this material system for state-of-the-art upconversion applications.

*Defense Advanced Research Projects Agency grant HR00112220010Part of this work was performed at the Stanford Nano Shared Facilities (SNSF), supported by the National Science Foundation under award ECCS-2026822YW acknowledges financial support from the Office of Naval Research (award N00014-19-1-2453). Use of the Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Contract No. DE-AC02-76SF00515.

Publication: This work is submitted to ACS Nano

Presenters

  • Manchen Hu

    • Stanford University

Authors

  • Manchen Hu

    • Stanford University
  • Emma Belliveau

    • Stanford University
  • Yilei Wu

    • Stanford University
  • Pournima Narayanan

    • Stanford University
  • Demeng Feng

    • University of Wisconsin-Madison, Madison
  • Rabeeya Hamid

    • University of Wisconsin-Madison, Madison
  • Natalia Murrietta

    • Stanford University
  • Ghada Ahmed

    • Stanford University
  • Mikhail A Kats

    • University of Wisconsin-Madison, Madison
  • Daniel N Congreve

    • Stanford University