Flow-induced switching between blue phases

ORAL

Abstract

Blue-phases (BPs) are highly ordered soft materials that appear in a narrow temperature range between the chiral nematic and the isotropic phases. BPs exhibit cubic arrangements of double-twist cylinders and disclination lines with characteristic length scales of the wavelength of visible light. Between BPI and BPII exist topological differences which are significantly responsible for their different dynamical response under external stimuli. Here we focus on the dynamic and out-of-equilibrium states of BPII under shear stresses in pressure-driven flow inside microfluidic channels. We show in experiments how precise tuning of the driving pressure on BPII with the lattice orientation (111) can be used to stabilize and manipulate a previously unresearched switching state between BPII and BPI. Combining experiments with simulations, we try to understand the dynamics of disclinations lines and how they are affected by hydrodynamic forces. We also characterize the sequence of all dynamical, flow-induced out-of-equilibrium regimes when subject to a pressure-driven flow in a microfluidic geometry with controlled anchoring conditions.

*We acknowledge support by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division.

Presenters

  • Tadej Emersic

    • University of Chicago, Pritzker School of Molecular Engineer

Authors

  • Tadej Emersic

    • University of Chicago, Pritzker School of Molecular Engineer
  • Rui Zhang

    • HKUST
    • The Hong Kong University of Science and
    • Hong Kong University of Science and Technology
    • The Hong Kong University of Science and Technology
  • José A Martínez-González

    • Facultad de Ciencias, Universidad Autónoma de San Luis Potosí, Mexico
  • Kushal Bagchi

    • University of Chicago
  • Paul F Nealey

    • University of Chicago
  • Juan J De Pablo

    • University of Chicago