Employing a novel approach for a controlled fabrication of 1D nanowires on suspended microstructures of arbitrary geometries using two direct-writing technologies

POSTER

Abstract

Recent progresses in additive manufacturing have inspired new technologies, such as the direct laser writing technique based on two-photon polymerization (2PP), which complements and further enriches the nanofabrication tools portfolio. In this study, we combine 2PP and our mask-free scanning probe-assisted "direct-write patterning" method to allow for: a) the fabrication of micro-bridge structures with the sub-micrometer resolution, b) selective synthesis of crystalline ZnO nanowires at predefined locations, respectively. This synergistic approach enables cantilever probe patterning of catalysts directly on suspended micro-bridges for CVD growth of nanoscale material in a templated manner. This work represents the first proof-of-concept experiment demonstrating a versatile and scalable methodology. Our method is adaptable and simply scalable to grow a variety of other nanomaterials in a controlled and selective manner on size-independent micro/nanoscale structures. The possibility of integrating this new approach with conventional lithography techniques provides a step forward to developing a novel class of hybrid polymer-silicon-1D or -2D materials and systems. The quality of the ZnO nanowire assemblies was assessed using several physical characterization methods.

*Use of the Center for Nanoscale Materials was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Contract No. DE-AC02 06CH11357. A portion of this research was conducted at the ONRL Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility. IK acknowledges support of SLU seed funds.

Publication: K. McCormack, N. Schaper, Y. Kim, D.K. Hensley, I. Kravchenko, N.V. Lavrik, D.J. Gosztola, M.F. Pantano, I. Kuljanishvili,
Enabling a novel approach to a controlled fabrication of 1D crystalline nanowires on suspended microstructures of arbitrary geometries using two direct-writing technologies, Materials Today Nano, Volume 20, 2022, 100241, https://doi.org/10.1016/j.mtnano.2022.100241.

Presenters

  • Nicholas J Schaper

    • Saint Louis University

Authors

  • Nicholas J Schaper

    • Saint Louis University
  • Irma Kuljanishvili

    • Saint Louis University
  • YOOSUK KIM

    • Department of Physics, Saint Louis University
    • Saint Louis University
  • Keith X McCormack

    • Saint Louis University
  • Ivan I Kravchenko

    • Oak Ridge National Laboratory
    • Oak Ridge National Labs, Center for Nanophase Materials
  • David Gosztola

    • Argonne National Labs
  • Maria Pantano

    • University of Trento
  • Nickolay Lavrik

    • Oak Ridge National Laboratory
  • Dale K Hensley

    • Oak Ridge National Laboratory