Detecting Magnetic Switching in Single-Molecule Magnet Mn<sub>12</sub> using Graphene Quantum Dots

ORAL

Abstract

Transport measurements through a graphene quantum dot device decorated with single-molecule magnet (SMM) Mn12 powder indicate stochastic switching of the magnetization in the molecules. Here we show that discrete changes in the graphene conductance can be attributed to magnetic switching of the molecules. The local magnetic field causes a change in the activation energy of the hot electrons in the quantum dot [1], allowing the graphene device to serve as a sensitive detector for the spin state of the proximate molecules and as a probe to measure the interaction between the SMMs and the graphene. The size of the activation energy change is too large to be explained by Zeeman effects owing to the dipole field, suggesting an exchange bias interaction between the graphene and the molecules.



[1] A. El Fatimy et al. Nature Nanotechnology 11, 335-338 (2016)

*This work was funded by the National Science Foundatation and the Ofice of Naval Research

Presenters

  • DaVonne Henry

    • Georgetown University

Authors

  • DaVonne Henry

    • Georgetown University
  • Amjad Alqahtani

    • Georgetown University
  • luke st marie

    • Georgetown University
  • Samuel I Felsenfeld

    • University of Maryland, College Park
  • Lubomir Havlicek

    • Central European Institute of Technology, Brno Unversity of Technology
    • CEITEC, Brno University of Technology
  • Jakub Hruby

    • National High Magnetic Field Laboratory
  • Antonin Sojka

    • Central European Institute of Technology, Brno Unversity of Technology
  • Jorge Navarro

    • Central European Institute of Technology, Brno Unversity of Technology
  • Abdelouahad El Fatimy

    • Institute of Applied Physics, Mohammed VI Polytechnic University, Lot 660, Hay Moulay Rachid, Ben Guerir, 43150, Morocco.
    • Mohammed VI Polytechnic University
  • Rachael L Myers-Ward

    • US Naval Research Laboratory
    • U.S. Naval Research Laboratory
  • David K Gaskill

    • University of Maryland
    • U.S. Naval Reserach Laboratory
    • U.S. Naval Research Laboratory
  • Daniel Pennachio

    • US Naval Research Laboratory
    • U.S. Naval Reserach Laboratory
    • U.S. Naval Research Laboratory
  • Jenifer Hajzus

    • US Naval Research Laboratory
    • U.S. Naval Reserach Laboratory
    • ASEE Research Associate at the U.S. Naval Research Laboratory
  • Albert F Rigosi

    • National Institute of Standards and Technology
    • NIST
  • Ivan Nemec

    • Central European Institute of Technology
    • CEITEC, Brno University of Technology
  • Petr Neugebauer

    • brno university of Technology, CEITEC
    • Central European Institute of Technology, CEITEC BUT, Purkynova 656/123, Brno 61200, Czech Republic
    • Central European Institute of Technology
    • CEITEC, Brno University of Technology
  • Amy Y Liu

    • Georgetown University
  • Paola Barbara

    • Georgetown University
    • Department Physics, Georgetown University