Fragile to strong crossover in a model glass-former

ORAL

Abstract

Glass-forming liquids are broadly classified fragile and strong glass-forming liquids, which show non-Arrhenius and Arrhenius temperature dependence of dynamics, respectively, as the glass transition temperature is approached. In liquids like water or silica, a fragile to strong crossover is observed at lower temperatures. Though, most metallic glass-formers show fragile behaviour for a wide range of temperatures, it has recently been found that even metallic glass-forming liquids show a fragile to strong crossover in dynamics when really low temperatures are accessed.  In our work, we have computationally studied the Kob-Andersen model for a wide range of temperatures and have accessed really low temperatures below the mode coupling temperature(TMCT). We find signatures of a possible fragile to strong dynamical crossover below TMCT consistent with the previous findings in different metallic glass formers. We investigate aspects of dynamical heterogeneity and thermodynamics accompanying this crossover.

*We acknowledge the Thematic Unit of Excellence on ComputationalMaterials Science, and the National Supercomputing Mission facility (ParamYukti) at the Jawaharlal Nehru Center for Advanced Scientific Research forcomputational resources. SS acknowledges support through the JC BoseFellowship (JBR/2020/000015) SERB, DST (India).

Publication: None

Presenters

  • Pallabi Das

    • JNCASR

Authors

  • Srikanth Sastry

    • Jawaharlal Nehru Centre for Advanced Sci
  • Pallabi Das

    • JNCASR