Elastic Fluctuations can drive Ferroelectric Transitions Incommensurate

ORAL

Abstract

We consider a Ginzburg-Landau theory for a ferroelectric phase transition whose primary order parameter (electrical polarization) is coupled to elastic strain through electrostriction. We show that the strain coupling leads to a quartic term in the effective Hamiltonian that describes long-range, anisotropic interactions between fluctuations in the order parameter. At the level of mean field theory plus Gaussian fluctuations, we demonstrate that the ferroelectric instability is driven to a finite wavevector, so that the transition from the disordered phase to the fully ordered ferroelectric phase must occur via an incommensurate phase.

*C.H.L. acknowledges support from NSF GRFP DGE-1746045. G.G.G.-V. acknowledges support from the Vice-rectory for Research at the University of Costa Rica (project No. 816-C1-601). Work at Argonne is supported by DOE Office of Science, BES-MSE under Contract No. DE-AC02-06CH11357.

Presenters

  • Charles H Liang

    • University of Chicago

Authors

  • Charles H Liang

    • University of Chicago
  • Gian G Guzmán-Verri

    • Univ de Costa Rica
    • Universidad de Costa Rica
  • Peter B Littlewood

    • University of Chicago