Materials genes of heterogeneous catalysis from clean experiments and artificial intelligence

ORAL

Abstract

Heterogeneous catalysis is an example of a complex materials function governed by an intricate interplay of several processes. While modeling the full catalytic progression via first-principles statistical mechanics is impractical, we show how a tailored artificial-intelligence approach can be applied, even to a small number of materials, to determine the key descriptive parameters or materials genes reflecting the processes that trigger, facilitate, or hinder catalyst performance. We start from a consistent experimental set of clean data,[1] containing 12 selective-oxidation catalysts which were synthesized, fully characterized, and tested according to standardized protocols. Then, we apply the symbolic-regression SISSO approach[2] to identify the few most relevant materials properties that correlate, in a possibly nonlinear way, with the reactivity.[3]

*L.F. acknowledges the funding from the Swiss National Science Foundation, postdoc mobility Grant P2EZP2_181617 and the NOMAD CoE (European Union's Horizon 2020 research and innovation program under the Grant Agreement No. 951786).

Publication: [1] A. Trunschke, et al., Top. Catal. 63, 1683-1699 (2020).
[2] R. Ouyang, et al., Phys. Rev. Mater. 2, 083802 (2018).
[3] L. Foppa, et al., MRS Bull. 46, 1 (2021).

Presenters

  • Matthias Scheffler

    • NOMAD Laboratory, Fritz Haber Institute of the Max Planck Society
    • Fritz-Haber Institute
    • The NOMAD Laboratory at the Fritz Haber Institute of the MPG

Authors

  • Lucas Foppa

    • Fritz-Haber Institute
  • Luca M Ghiringhelli

    • Fritz Haber Institute
    • Fritz-Haber-Institute, MPS, Berlin, Germany
    • Fritz-Haber Institute
    • NOMAD Laboratory at the Fritz Haber Institute and Humboldt University
  • Frank Girgsdies

    • Fritz Haber Institute
  • Maike Hashagen

    • Fritz Haber Institute
  • Pierre Kube

    • Fritz Haber Institute
  • Michael Hävecker

    • Max Planck Institute for Chemical Energy Conversion
  • Spencer J. Carey

    • Fritz Haber Institute
  • Andrey Tarasov

    • Fritz Haber Institute
  • Peter Kraus

    • Fritz Haber Institute
  • Frank Rosowski

    • BASF SE
  • Robert Schlögl

    • Fritz Haber Institute
  • Annette Trunschke

    • Fritz Haber Institute
  • Matthias Scheffler

    • NOMAD Laboratory, Fritz Haber Institute of the Max Planck Society
    • Fritz-Haber Institute
    • The NOMAD Laboratory at the Fritz Haber Institute of the MPG