Progress in numerical modeling of near-field infrared phenomena at nanometer length scales

ORAL

Abstract

The extraction of meaningful nanoscale material properties is reliant on proper modeling of the experimental spectra obtained with broadband, near-field infrared nanospectroscopy. We will discuss our progress towards this goal by presenting combined experimental and numerical modeling results on materials with diverse properties and geometries.. Strong coupling of light to the probe-sample system in highly polar dielectrics such as SrTiO3 leads to multiple phonon-polariton resonances. We show that these resonances should be described by detailed numerical simulations1. We obtain near-field infrared spectra on Cu2S nanoplatelets and show that numerical modeling of the spectra is indispensable for obtaining the properties of nanomaterials. Furthermore, many materials have anisotropic dielectric functions. We have obtained near-field infrared spectra on a uniaxial rutile TiO2 crystal. Proper modeling of spectra from anisotropic materials also requires meticulous numerical simulations.

1 P. McArdle, D.J. Lahneman, A. Biswas, F. Keilmann, and M.M. Qazilbash, Phys. Rev. Res. 2, 023272 (2020).

*M.M.Q. acknowledges support from the National Science Foundation (NSF). Simulation work was performed, in part, using computing facilities at the College of William & Mary.

Presenters

  • Patrick McArdle

    • Department of Physics, William & Mary
    • Department of Physics, College of William & Mary

Authors

  • Patrick McArdle

    • Department of Physics, William & Mary
    • Department of Physics, College of William & Mary
  • David Lahneman

    • Department of Physics, William & Mary
    • Department of Physics, College of William & Mary
  • Haoyue Jiang

    • Department of Physics, William & Mary
    • Department of Physics, College of William & Mary
  • Muhammad M Qazilbash

    • Department of Physics, William & Mary
    • Department of Physics, College of William & Mary
  • Tetiana Slusar

    • Metal-Insulator Transition Laboratory, ETRI
    • Metal-Insulator Transition Laboratory, Electronics and Telecommunications Research Institute
  • Hyun-Tak Kim

    • Electronics & Telecommunications Research Institute
    • Metal-Insulator Transition Laboratory, ETRI
    • Metal-Insulator Transition Laboratory, Electronics and Telecommunications Research Institute
    • MIT Lab, ETRI in Korea
  • Amlan Biswas

    • University of Florida
    • Department of Physics, University of Florida
  • Fritz Keilmann

    • Fakultat fur Physik & Center for NanoScience (CeNs), Ludwig-Maximilians-Universitat
    • Fakultät für Physik & Center for NanoScience (CeNS), Ludwig-Maximilians-Universität
  • Jingyi Chen

    • Department of Chemistry and Biochemistry, University of Arkansas