Length scales of interfacial coupling between metal and insulator phases in oxides

ORAL

Abstract

Understanding the mechanisms that control the metal to insulator transition (MIT) in correlated electron systems is one of the major challenges in condensed matter physics. Moreover, remarkably little is known about the characteristic lengths scale over which a metallic or insulating region can be established and the physics that sets this length scale. In this work, we use experimental and theoretical methods to design and study superlattices of two distinct rare earth nickelate oxides SmNiO3 and NdNiO3 that in bulk form show a MIT at two very different temperatures (400 K and 200 K, respectively). We find that, depending on the superlattice periodicity, these new complex oxide superlattices display different MIT behavior than that of the "bulk" materials. We show that the length scale of the metal-insulator transition in the superlattices is set not by the length scale of the propagation of structural motifs across the two materials, which ab-initio calculations and STEM analysis suggest is minimal, but rather by the balance between the energy cost of the boundary between a metal and an insulator and the energy gain of the bulk phases (Domínguez, C., Georgescu, A.B., Mundet, B. et al. Nat. Mater. 19, 1182–1187 (2020)).

Presenters

  • Claribel Dominguez Ordonez

    • Department of quantum matter physics, Univ of Geneva
    • Univ of Geneva

Authors

  • Claribel Dominguez Ordonez

    • Department of quantum matter physics, Univ of Geneva
    • Univ of Geneva
  • Alexandru Bogdan Georgescu

    • McCormick School of Engineering, Department of Materials Science and Engineering, Northwestern University
    • Simons Foundation
    • Center for Computational Quantum Physics, Flatiron Institute
    • McCormick School of Engineering, Department of Materials Science & Engineering, Northwestern University
  • Bernat Mundet

    • Department of quantum matter physics, Univ of Geneva
    • Univ of Geneva
  • Yajun Zhang

    • Theoretical Materials Physics, Q-MAT, CESAM, University of Liège
  • Alain Mercy

    • Theoretical Materials Physics, Q-MAT, CESAM, University of Liège
  • Jennifer Fowlie

    • Department of Quantum Matter Physics, University of Geneva
    • Department of quantum matter physics, Univ of Geneva
    • Univ of Geneva
  • Sara Catalano

    • Univ of Geneva
  • Duncan T.L. Alexander

    • Electron Spectrometry and Microscopy Laboratory, EPFL, Lausanne
    • LSME, École Polytechnique Fédérale de Lausanne (EPFL)
    • LSME, EPFL
  • Philippe Ghosez

    • Theoretical Materials Physics, Q-MAT, CESAM, University of Liège
  • Andrew Millis

    • Columbia University
    • Department of Physics, Columbia University
    • Flatiron Institute
    • Columbia Univ
    • Center for Computational Quantum Physics, Flatiron Institute
    • Flatiron Institute; Columbia Univ.
    • Columbia University and Center for Computational Quantum Physics, Flatiron Institute
  • Antoine Georges

    • Center for Computational Quantum Physics, Flatiron Institute
    • Flatiron Institute
  • Marta Gibert

    • University of Zurich
    • Univ of Zurich
    • Physik-Institut, University of Zurich
  • Jean-Marc Triscone

    • Department of Quantum Matter Physics, University of Geneva
    • Department of quantum matter physics, Univ of Geneva
    • Univ of Geneva