Charge density wave in BaFe<sub>2</sub>Al<sub>9</sub>

ORAL

Abstract

Charge density waves (CDW) are modulations of the crystal lattice that develop in crystalline materials on cooling. Generally, CDW compounds have strongly 1-d or 2-d character. In contrast, BaFe2Al9 is a hexagonal intermetallic compound with a distinctly 3-d electronic structure. Despite this, a hysteretic phase transition is observed in single crystals centered around 100K in magnetic susceptibility and resistance measurements. Diffraction and Mössbauer experiments reveal this transition is due to the formation of a CDW via a first order phase transition with a large lattice strain (-1.5% along the c-axis). Details of this modulated phase will be discussed as well as why charge order is favored over magnetic order in this metallic, iron-containing compound.

*Research supported by the U. S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division. This research used resources at the Spallation Neutron Source, a DOE Office of Science User Facility operated by Oak Ridge National Laboratory.

Presenters

  • William Meier

    • Ames Laboratory, Iowa State University, Ames; Oak Ridge National Laboratory, Oak Ridge
    • Oak Ridge National Lab

Authors

  • William Meier

    • Ames Laboratory, Iowa State University, Ames; Oak Ridge National Laboratory, Oak Ridge
    • Oak Ridge National Lab
  • Bryan C Chakoumakos

    • Oak Ridge National Lab
  • Andrew Christianson

    • Oak Ridge National Lab
    • Materials Science & Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA
    • Oak Ridge National Laboratory
  • Qiang Zhang

    • Oak Ridge National Laboratory
    • SNS, Oak Ridge National Laboratory
    • Oak Ridge National Lab
  • Shang Gao

    • Oak Ridge National Lab
  • Matthew Brandon Stone

    • Oak Ridge National Lab
    • Oak Ridge national lab
    • Quantum Condensed Matter Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA
    • Neutron Scattering Division, Oak Ridge National Laboratory
    • Oak Ridge National Laboratory
    • Oakridge National Laboratory
  • Satoshi Okamoto

    • Oak Ridge National Lab
    • Materials Science and Technology Division, Oak Ridge National Laboratory
    • Oak Ridge National Laboratory
  • German D Samolyuk

    • Oak Ridge National Lab
  • Raphael Hermann

    • Oak Ridge National Lab
    • Oak Ridge National Laboratory
  • Michael A McGuire

    • Materials Science and Technology Division, Oak Ridge National Laboratory
    • Oak Ridge National Lab
    • Oak Ridge National Laboratory
  • Brian Craig Sales

    • Oak Ridge National Lab