Device Integration of Atomically precise Graphene Nanoribbons (GNRs)

ORAL

Abstract

Graphene nanoribbons (GNRs) have attracted considerable interest due to their largely modifiable electronic properties, including width-dependent bandgaps for armchair GNRs and spin-polarized edge states for GNRs with zigzag edges.1,2,3,4 Manifestation of these properties requires atomically precise GNRs, which can be achieved through a bottom-up synthesis approach under ultrahigh vacuum conditions. We show that 5-atom wide armchair GNRs as well as pyrene-GNRs can be processed under ambient conditions and incorporated as the active material in a field effect transistor.5,6 At room temperature, a film like behavior is observed while at cryogenic temperatures coulomb blockade and single electron tunnelling can be seen. Our recent results may enable the realization of devices based on carbon nanomaterials with exotic quantum properties.

1 Cai, J. et al., Nature 466, 470–473, (2010)
2 Chen, Y.-C et al., ACS Nano 7, 7, 6123–6128, (2013)
3 Ruffieux, P. et al., Nature 531, 489–492, (2016)
4 Gröning, O. et al., Nature 560, 209–213, (2018)
5 El Abbassi, M. et al., ACS Nano, 14, 5, 5754–5762 (2020)
6 Sun, Q. et al., Advanced Materials, 32, 1906054 (2020)

*This work was supported by European Union under grant agreement no. 767187 (QuIET).

Presenters

  • Oliver Braun

    • Empa, Swiss Federal Laboratory for Materials Science and Technology

Authors

  • Oliver Braun

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Jan Overbeck

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Mickael Perrin

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Gabriela Borin Barin

    • Empa, Swiss Federal Laboratories for Materials Science and Technology
    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Maria El Abbassi

    • Department of Quantum Nanoscience, Delft University of Technology
  • Qiang Sun

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Sara Sangtarash

    • Engineering, Warwick University
    • School of Engineering, University of Warwick
  • Akimitsu Narita

    • Max Planck Institute for Polymer Research, Mainz, Germany
    • Max Planck Institute for Polymer Research
  • Klaus Müllen

    • Max Planck Institute for Polymer Research, Mainz, Germany
    • Max Planck Institute for Polymer Research
  • Kristjan Eimre

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Edward Ditler

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Colin R Daniels

    • Rensselaer Polytechnic Institute
  • Vincent Meunier

    • Rensselaer Polytechnic Institute
  • Carlo Antonio Pignedoli

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Hatef Sadeghi

    • Engineering, Warwick University
    • School of Engineering, University of Warwick
  • Colin Lambert

    • Physics, Lancaster University
    • Department of Physics, Lancaster University
  • Oliver Gröning

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Pascal Ruffieux

    • Empa, Swiss Federal Laboratories for Materials Science and Technology
    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Roman Fasel

    • Empa, Swiss Federal Laboratories for Materials Science and Technology
    • Empa, Swiss Federal Laboratory for Materials Science and Technology
  • Michel Calame

    • Empa, Swiss Federal Laboratory for Materials Science and Technology
    • Materials Science and Technology, EMPA