Spectroscopic signatures of few- and single layer <i>M</i>PS<sub>3</sub> (<i>M</i>= Mn, Ni, Fe) complexes

ORAL

Abstract

Layered magnetic chalcogenides have become increasingly important over the last decade because they offer a unique platform for combining the complexity of bulk materials with the tunability of few- and single layer systems. These van der Waals complexes have been well studied by Raman spectroscopy, however, infrared spectroscopy is vastly underexplored due to the inability to overcome the diffraction limit. It is these ungerade infrared active modes that are vital in understanding material functionality. Synchrotron infrared nanospectroscopy, a fusion of near-field optical microscopy with high brightness infrared synchrotron radiation, has overcome this fight for photons and enabled a better understanding of size-induced effects, including symmetry breaking, that are quite different from the single crystal. This approach will be illustrated with members of the MPS3 (M= Mn, Ni, Fe) family of complex chalcogenides.

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Presenters

  • Sabine Neal

    • Chemistry, University of Tennessee, Knoxville
    • Department of Chemistry, University of Tennessee, Knoxville

Authors

  • Sabine Neal

    • Chemistry, University of Tennessee, Knoxville
    • Department of Chemistry, University of Tennessee, Knoxville

  • Heung Sik Kim

    • Department of Physics, Kangwon University

  • Kenneth R O'Neal

    • Chemistry, University of Tennessee, Knoxville
    • University of Tennessee, Knoxville
    • Department of Chemistry, University of Tennessee, Knoxville

  • Amanda Haglund

    • Department of Materials Science and Engineering, University of Tennessee

  • Kevin Arthur Smith

    • Chemistry, University of Tennessee, Knoxville
    • Department of Chemistry, University of Tennessee, Knoxville
    • Chemistry, University of Tennessee, Knoxville, Tennessee, 37996, USA

  • David Mandrus

    • Physics, University of Tennessee
    • Materials Science and Engineering, The University of Tennessee
    • Department of Materials Science & Engineering, University of Tennessee, Knoxville
    • The University of Tennesse, Knoxville
    • University of Tennessee
    • Department of Physics and Astronomy, University of Tennessee
    • Oak Ridge National Laboratory
    • Department of Materials Science and Engineering, University of Tennessee Knoxville
    • Department of Materials Science and Engineering, University of Tennessee
    • University of Tennessee, Knoxville
    • Material Science and Technology Division, Oak Ridge National Laboratory
    • Material Science and Technology Division, Oak Ridge National Lab

  • Hans Bechtel

    • Advanced Light Source Division, Lawrence Berkeley National Lab
    • Lawrence Berkeley National Lab
    • Lawrence Berkeley National Laboratory

  • G Carr

    • National Synchrotron Light Source II, Brookhaven National Lab
    • Brookhaven National Lab
    • Brookhaven National Laboratory

  • Kristjan Haule

    • Department of Physics & Astronomy, Rutgers University
    • Dept. of Physics and Astronomy, Rutgers University, New Brunswick
    • Rutgers University, New Brunswick
    • Rutgers Univeristy
    • Department of Physics and Astronomy, Rutgers University, Piscataway, NJ, United States
    • Department of Physics and Astronomy, Rutgers University
    • Rutgers University
    • Physics, Rutgers University
    • Physics & Astronomy, Rutgers University, New Brunswick, NJ, USA 08854

  • David Vanderbilt

    • Department of Physics and Astronomy, Piscataway, NJ 08854, Rutgers University
    • Department of Physics and Astronomy, Rutgers University, New Brunswick, NJ, USA
    • Department of Physics & Astronomy, Rutgers University
    • Physics and Astronomy, Rutgers University
    • Department of Physics and Astronomy, Rutgers University
    • Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854, USA
    • Department of Physics and Astronomy, Rutgers University, Piscataway, NJ, United States
    • Rutgers University
    • Physics, Rutgers University
    • Department of Physics and Astronomy, Rutgers University, New Brunswick
    • Rutgers University, New Brunswick

  • Janice Lynn Musfeldt

    • University of Tennessee
    • Department of Chemistry, University of Tennessee, Knoxville
    • Chemistry, University of Tennessee, Knoxville
    • University of Tennessee, Knoxville
    • Chemistry, University of Tennessee, Knoxville, Tennessee, 37996, USA