Exploring the Magnetic Properties of the Iron-Nitrogen System

ORAL

Abstract

The magnetic properties of the iron-nitrogen system have only been explored on a very limited basis. Theoretical predictions of the magnetic behavior of the different phases of iron nitride are limited and experimental data is quite sparse. By employing several different techniques which include solution based nanoparticle nitridation, electrochemical methods, and metathesis based reactions we have synthesized several different phases of iron nitride: FeN, Fe2N, Fe3N, Fe4N, and Fe24N10. Additionally, we have demonstrated a path for consolidating raw powders of iron nitride into bulk material, enabling additional characterization and application in macroscopic devices. Our difficulties and successes in synthesizing and processing these different phases of iron nitride will be described. Additionally, the magnetic properties of these seldom explored iron-nitrogen compounds will be summarized.

*Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia, LLC., a wholly owned subsidiary of Honeywell International, Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

Presenters

  • Todd Monson

    • Sandia National Laboratories

Authors

  • Todd Monson

    • Sandia National Laboratories
  • Tyler Stevens

    • Sandia National Laboratories
  • Stan Atcitty

    • Sandia National Laboratories
  • Baolong Zheng

    • University of California, Irvine
  • Yizhang Zhou

    • University of California, Irvine
  • Enrique Lavernia

    • University of California, Irvine