Comparative Study of Surface Structural and Physical Properties of Sr<sub>3</sub>T<sub>2</sub>O<sub>7</sub> (T = Mn, Ru)
ORAL
Abstract
Double-layered Ruddlesden-Popper oxides are known to exhibit a strong correlation between octahedral distortion and physical properties. Using low-energy electron diffraction (LEED) and high-resolution electron energy loss spectroscopy (HREELS), we have investigated the surface structural and physical properties of Sr3T2O7 (T = Mn, Ru). While surface RuO6 octahedron in Sr3Ru2O7 has both rotation (~ 12°) and tilt (~ 3°), our LEED – IV analysis reveals that MnO6 octahedron in Sr3Mn2O7 has a similiar rotation (~ 11°) but no tilt. HREELS data suggest that both the surface of Sr3Mn2O7 and Sr3Ru2O7 are semiconducting but for different reasons. The implication of these findings will be discussed.
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Presenters
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Yifan Yang
- Louisiana State University