Comparing Bulk and Layer Confined RNiO<sub>3</sub> to Disentangle Lattice and Electronic Effects in the Metal-Insulator Transition

ORAL

Abstract

The metal-insulator transition (MIT) of transition metal oxides is often associated with a simultaneous lattice and electronic symmetry breaking. We disentangle the effects of the electronic and lattice structure in the MIT of rare earth nickelates (RNiO3) by comparing bulk and layer-confined NdNiO3, using a combination of electronic structure and many-body methods[1,2,3]. We find that electronic confinement leads to an increase in the relative role of local interactions that favor an insulating symmetry-broken state. However, heterostructuring with another material leads to an increase in the lattice stiffness with respect to structural disproportionation caused by the interfacial octahedral coupling. Our work explains why nickelate heterostructures can have both a higher MIT temperature despite a weaker structural signature of the insulating state[4]. These results are of general relevance to the physics of transition-metal oxides.
[1]AB Georgescu et al arXiv:1810.00480
[2]OE. Peil et al arXiv:1809:03720
[3]Q Han and AJ Millis PRL 121, 067601(2018)
[4]A Disa et al PRM 1,024410(2017)

*The Flatiron Institute is a division of the Simons Foundation.AG acknowledges the support of the European Research Council (ERC-319286-QMAC).OEP acknowledges FFG COMET program IC-MPPE (No 859480)

Presenters

  • Alexandru Bogdan Georgescu

    • Center for Computational Quantum Physics, The Flatiron Institute
    • Center for Computational Quantum Physics, Flatiron Institute, NY, NY, 10010

Authors

  • Alexandru Bogdan Georgescu

    • Center for Computational Quantum Physics, The Flatiron Institute
    • Center for Computational Quantum Physics, Flatiron Institute, NY, NY, 10010
  • Oleg E. Peil

    • Materials Center, Leoben, Austria
  • Ankit S Disa

    • Max Planck Institute, Hamburg, Germany
  • Antoine Georges

    • Collège de France
    • College de France
    • CCQ, Flatiron Institute, Simons Foundation
    • Center for Computational Quantum Physics, Flatiron Institue
    • Flatiron Institute - Simons Foundation, New York, USA
    • Center for Computational Quantum Physics, Flatiron Institute, NY, NY, 10010
    • CCQ, Flatiron Institute
    • Center for Computational Quantum Physics, Flatiron Institute
  • Andrew Millis

    • Center for Computational Quantum Physics, Flatiron Institute
    • Physics, Columbia University
    • Columbia University
    • Department of Physics, Columbia University
    • Center for Computational Quantum Physics, Flatiron Institute, NY, NY, 10010
    • National Institute of Materials Science
    • Center for Computational Quantum Physics, Flatiorn Institute, Physics Department, Columbia University