NMR Studies of the Vanadium Phosphorous Oxide Single Crystal
ORAL
Abstract
Strongly correlated-electron system, vanadium phosphorous oxide (VxPOy), have shown a variety of crystal structures and distinct magnetic properties, depending on the different stoichiometric ratio x and y and the valence states on V sites. A recently synthesized member of the VxPOy family was observed to undergo two phase transitions, through transport, magnetic susceptibility and neutron scattering measurements. The low-temperature phase (T<130 K) is a canted antiferromagnet, while 13P NMR spectroscopy and relaxation in the intermediate phase (130 K<T<615 K) is consistent with paramagnetism. The transition at 615 K is of unknown origin, but may be associated with charge or orbital ordering in the system.
*Work at UCLA was supported by NSF award DMR-1629457.
–
Presenters
-
Chaowei Hu
- University of California, Los Angeles
- Physics and Astronomy, Univ of California - Los Angeles