Roughening Temperature of Facets in Au Electrodeposition

ORAL

Abstract

A theory has been established to describe the formation of facets on metal crystals grown from their melt. There exists a temperature for each crystallographic orientation below which it will form a facet, and above which the metal surface will be rounded and atomically rough. Here we have extended this theory to electrodeposition. We used potentiostatic electrochemical impedance spectroscopy to measure the approximate surface energy of Au at different applied potentials to determine the roughening temperature for each potential.

*This material is based upon work supported by the National Science Foundation Graduate Research Fellowship under Grant No. (DGE-1258923).

Presenters

  • Nathan Nesbitt

    • Physics, Boston College

Authors

  • Nathan Nesbitt

    • Physics, Boston College
  • Samantha Jaszewski

    • Physics, Boston College
    • Boston College
  • Yitzi Calm

    • Physics, Boston College
  • Luke D'Imperio

    • Physics, Boston College
  • Aaron Rose

    • Physics, Boston College
  • Steve Shepard

    • Integrated Sciences Cleanroom and Nanofabrication Facility, Boston College
  • Michael Burns

    • Physics, Boston College
  • Fazel Fallah Tafti

    • Physics, Boston College
  • Wilson Smith

    • Chemical Engineering, TU Delft
  • Michael Naughton

    • Physics, Boston College
    • Department of Physics, Boston College