Single Nano-Particle Plasmons, Catalysis, and Substrate Engineering Studied with Synchrotron Infrared Nano-Spectroscopy

ORAL

Abstract

Synchrotron infrared nano-spectroscopy (SINS) combines the low-noise, broadband, high spectral irradiance, and coherence of synchrotron infrared radiation with scattering type, scanning near-field optical microscopy (s-SNOM) to enable sensitive vibrational spectroscopy spanning the entire mid- and far-infrared regions with nanometer spatial resolution. This powerful combination empowers a qualitatively new form of nano-chemometric analysis. The Advanced Light Source (ALS) at Berkeley Lab operates two infrared beamlines with SINS instruments that are available to general users. Here, we highlight three studies. First, Johns et al.1 use SINS to measure narrow plasmonic linewidths of single doped metal oxide nanocrystals. Second, Wu et al.2 use SINS to measure chemical reactions on single particle gold and platinum catalysts, revealing site specific enhancement of reactivity. Finally, Gilbert et al.3 studied engineered localized strain to control VO2 thin films and study them with SINS and x-ray microdiffraction.
[1] Johns, R.W., et al., Nature Commun. 7, 11583 (2016).
[2] Wu, C.-Y., et al., Nature 541, 511–515 (2017).
[3] Gilbert, S.N., et al., Phys. Rev. B 96, 161110(R) (2017).

*The Advanced Light Source is a DOE Office of Science User Facility under Contract No. DE-AC02-05CH11231.

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Presenters

  • Michael Martin

    • Advanced Light Source, Lawrence Berkeley National Laboratory

Authors

  • Michael Martin

    • Advanced Light Source, Lawrence Berkeley National Laboratory

  • Hans Bechtel

    • Advanced Light Source Division, Lawrence Berkeley National Lab
    • Advanced Light Source, Lawrence Berkeley National Laboratory
    • Advanced Light Source, Lawrence Berkeley Laboratory

  • Omar Khatib

    • Advanced Light Source, Lawrence Berkeley National Laboratory

  • Markus Raschke

    • Department of Physics, Department of Chemistry, JILA, and Center for Experiments on Quantum Materials, Univ of Colorado - Boulder
    • Physics, Chemistry, and JILA, University of Colorado Boulder
    • Department of Physics, Department of Chemistry, and JILA, University of Colorado - Boulder
    • Physics, University of Colorado - Boulder
    • Physics, Chemistry, and JILA, University of Colorado at Boulder
    • Physics, Univ of Colorado - Boulder
    • Univ of Colorado - Boulder

  • Robert Johns

    • Chemical Engineering, University of Texas at Austin

  • Delia Milliron

    • Chemical Engineering, University of Texas at Austin
    • Chemical Engineering, University of Texas, Austin

  • Elad Gross

    • Institute of Chemistry and The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem

  • F. Toste

    • Department of Chemistry, University of California, Berkeley

  • Stephanie Gilbert Corder

    • Department of Physics, Stony Brook University

  • Tiger Tao

    • Department of Mechanical Engineering, University of Texas at Austin

  • Mengkun Liu

    • Department of Physics, Stony Brook University

  • G Carr

    • NSLS-II, Brookhaven
    • NSLS-II Photon Sciences, Brookhaven National Laboratory