Tunable Photonic Band Gaps in an Entropic Crystal

ORAL

Abstract

Materials adopting the diamond structure exhibit many useful properties across atomic and colloidal systems, and therefore have been a strong research focus in materials science. The desirable properties of the diamond structure pose an interesting opportunity for reconfigurable materials: can we create a material that naturally transitions reversibly to and from the diamond structure? Hypothetically, such a material could exhibit two states, an on state, in which it exhibits the striking properties tied to the diamond structure, and an off state, where one or more of these properties are no longer present. In this talk, we show that we can design a colloidal crystal from convex polyhedral particles with a complete photonic band gap in the on state, which disappears when the material is switched off by a shape- and pressure-induced phase transition.

Presenters

  • Rose Cersonsky

    • Macromolecular Science and Engineering Program, University of Michigan - Ann Arbor
    • Macromolecular Science and Engineering Program, University of Michigan

Authors

  • Rose Cersonsky

    • Macromolecular Science and Engineering Program, University of Michigan - Ann Arbor
    • Macromolecular Science and Engineering Program, University of Michigan
  • Julia Dshemuchadse

    • Department of Chemical Engineering, University of Michigan - Ann Arbor
    • Department of Chemical Engineering, University of Michigan
    • Department of Chemical Engineering, Univ of Michigan - Ann Arbor
    • Chemical Engineering, University of Michigan
  • James Antonaglia

    • Department of Physics, University of Michigan
    • Physics, University of Michigan
  • Greg Van Anders

    • Department of Physics, University of Michigan
    • Univ of Michigan - Ann Arbor
    • Department of Physics, Univ of Michigan - Ann Arbor
    • University Michigan
  • Sharon Glotzer

    • Chemical Engineering, Univ of Michigan - Ann Arbor
    • Univ of Michigan - Ann Arbor
    • Department of Chemical Engineering, University of Michigan - Ann Arbor
    • Department of Chemical Engineering, University of Michigan
    • Chemical Engineering, University of Michigan
    • Department of Chemical Engineering, Univ of Michigan - Ann Arbor