Evidence of Bose-Einstein condensation in a quantum magnet formed by free radical tetramers

ORAL

Abstract

Several experimental realizations of quantum magnets showing Bose-Einstein condensates (BEC) have been reported in the literature. The typical scenario invokes a ground state described by pairs of localized spins forming singlets. An external magnetic field acts as an effective chemical potential for triplet excitations that can subsequently form the BEC. The T versus H phase diagrams typically display a ``dome'' structure bounded by two critical fields and a field-dependent critical temperature.

In this work, we present experimental and theoretical evidence of Bose-Einstein condensation in an organic crystal formed of weakly interacting S=1/2 tetramers. We show that the physics can be described in terms of a fully rotational invariant system of quantum spins without frustration. Two BEC phases exist: at low fields, only the edge spins of each tetramer contribute to the condensate, while at high-fields, the order is determined by the two central spins. These unusual BECs are separated by a quantum state with half of the spins forming dimerized pairs, and the other half aligned in the direction of the field.

Presenters

  • Andres Saul

    • CINaM-CNRS UMR 7325 Campus de Luminy, Aix-Marseille University
    • Aix-Marseille University
    • CINaM/CNRS, Aix-Marseille University
    • CINaM/CNRS, Aix-Marseille Univ.

Authors

  • Andres Saul

    • CINaM-CNRS UMR 7325 Campus de Luminy, Aix-Marseille University
    • Aix-Marseille University
    • CINaM/CNRS, Aix-Marseille University
    • CINaM/CNRS, Aix-Marseille Univ.
  • Nicolas Gauthier

    • Département de Physique, Université de Montréal
  • Reza Askari

    • Département de Physique, Université de Montréal
  • Michel Cote

    • Univ of Montreal
    • University of Montreal
    • Physics, Université de Montréal
    • Département de Physique, Université de Montréal
    • Physics, Univ of Montreal
  • Thierry Maris

    • Département de Chimie, Université de Montréal
  • Christian Reber

    • Département de Chimie, Université de Montréal
  • Anthony Lannes

    • Université de Lyon
  • Dominique Luneau

    • Université de Lyon
  • Michael Nicklas

    • Max Planck Institute for Chemical Physics of Solids
  • Joseph Law

    • Helmholtz-Zentrum Dresden-Rossendorf
  • Elizabeth Green

    • Helmholtz-Zentrum Dresden-Rossendorf
  • Joachim Wosnitza

    • Helmholtz-Zentrum Dresden-Rossendorf
    • Hochfeld-Magnetlabor Dresden (HLD-EMFL), Helmholtz-Zentrum Dresden
  • Adrian Feiguin

    • Department of Physics, Northeastern University
  • Andrea Bianchi

    • Univ. of Montreal
    • Département de Physique, Université de Montréal