Controlling the vertical transport of photocarriers to the surface

ORAL

Abstract

Spatial control of the vertical transport of carriers from the bulk to the surface for photochemical processes could provide improved selectivity and efficiency. Here we exploit the intensity variations in the photoexciting beam to drive competing nonlinear optical processes, and thereby allow vertical carrier tranport in only selected regions within the photoexcited spot. Using time-resolved photoemission microscopy, we make a movie of the resulting spatially inhomogeneous photocarrier dynamics. Our work provides a new pathway to control charge and current distributions in space and time within an optical spot, with implications for photovoltaics, photocatalysis and semiconductor devices.

Presenters

  • E Laine Wong

    • Okinawa Inst of Sci & Tech
    • Femtosecond Spectrocopy Unit, Okinawa Inst of Sci & Tech

Authors

  • E Laine Wong

    • Okinawa Inst of Sci & Tech
    • Femtosecond Spectrocopy Unit, Okinawa Inst of Sci & Tech
  • Andrew Winchester

    • Okinawa Inst of Sci & Tech
    • Femtosecond Spectroscopy Unit, Okinawa Inst of Sci & Tech
  • Michael Man

    • Okinawa Inst of Sci & Tech
    • Femtosecond Spectrocopy Unit, Okinawa Inst of Sci & Tech
    • Femtosecond Spectroscopy Unit, Okinawa Institute of Science and Technology Graduate University
  • Vivek Pareek

    • Okinawa Inst of Sci & Tech
    • Femtosecond Spectroscopy Unit, Okinawa Inst of Sci & Tech
    • Femtosecond Spectrocopy Unit, Okinawa Inst of Sci & Tech
  • Julien Madéo

    • Okinawa Inst of Sci & Tech
    • Femtosecond Spectroscopy Unit, Okinawa Inst of Sci & Tech
    • Femtosecond Spectrocopy Unit, Okinawa Inst of Sci & Tech
    • Femtosecond Spectroscopy Unit, Okinawa Institute of Science and Technology Graduate University
  • Keshav Dani

    • Okinawa Inst of Sci & Tech
    • Femtosecond Spectroscopy Unit, Okinawa Inst of Sci & Tech
    • Femtosecond Spectrocopy Unit, Okinawa Inst of Sci & Tech
    • Femtosecond Spectroscopy Unit, Okinawa Institute of Science and Technology Graduate University