Direct observation of the layer-dependent electronic structure in phosphorene

ORAL

Abstract

Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new two-dimensional (2D) material that holds promise for electronic and photonic technology. Here we experimentally demonstrate that the electronic structure of few-layer phosphorene varies significantly with number of layers, in good agreement with theoretical predictions. The interband optical transitions cover a wide, technologically important spectrum range from visible to mid-infrared. In addition, few-layer phosphorene is observed to photoluminesce at energies that correlate well with the layer-dependent bandgap transitions. The strongly layer-dependent electronic structure of phosphorene, in combination with its high electrical mobility, gives it distinct advantages over other two-dimensional materials in electronic and opto-electronic applications.

Authors

  • Likai Li

    • Fudan University
  • Jonghwan Kim

    • Physics Department at UC Berkeley
  • Chenhao Jin

    • Physics Department at UC Berkeley
  • Guo Jun Ye

    • University of Science and Technology of China
  • Diana Y. Qiu

    • Physics Department at UC Berkeley and LBNL
  • Felipe H. da Jornada

    • Physics Department at UC Berkeley and LBNL
  • Zhiwen Shi

    • Physics Department at UC Berkeley
  • Long Chen

    • Chinese Academy of Science
  • Zuocheng Zhang

    • Fudan University
  • Fangyuan Yang

    • Fudan University
  • Kenji Watanabe

    • National Institute for Materials Science, Japan
  • Takashi Taniguchi

    • National Institute for Materials Science, Japan
  • Wencai Ren

    • Chinese Academy of Science
  • Steven G. Louie

    • Physics Department at UC Berkeley and LBNL
  • Xian Hui Chen

    • University of Science and Technology of China
  • Yuanbo Zhang

    • Fudan University
  • Feng Wang

    • Physics Department at UC Berkeley