Chiral amplification and sensing of chirality with lyotropic chromonic liquid crystals.

ORAL

Abstract

Due to the anisotropic elastic properties of lyotropic chromonic liquid crystals (LCLCs), a spontaneously twisted chiral structure has been reported in the achiral LCLCs system under cylindrical confinement. It is found that the handedness of chirality could be biased with a minute amount of a chiral additive. The entire system becomes ``homochiral'' and takes on the handedness of the additive. When 1{\%} by weight of L-glutamic acid was added to LCLCs in a cylinder, the LCLC sbecomes homochiral and possesses giant optical rotation. We explore the mechanism for this based on the ``sergeants-and-soldiers'' and the ``majority-rule'' principles known for organic molecular systems.

Authors

  • Mohan Srinivasarao

    • Georgia Institute of Technology
  • Jung Ok Park

    • Georgia Institute of Technology
  • Jinxin Fu

    • Georgia Institute of Technology
  • Karthik Nayani

    • Georgia Institute of Technology
  • Rui Chang

    • Georgia Institute of Technology