Charge conduction in partially fluorinated discotic liquid crystals

POSTER

Abstract

Motivated by the role of electrostatic interactions on stacking of partially fluorinated conjugated compounds, we present mobility measurements of, e.g., 1,4-difluoro-2,3,6,7,10,11-hexakispentaloxytriphenylene (2F-HAT5) in discotic mesophases across a wide range of temperature and applied electric field. Charge conduction in this case is well described by a disorder driven hopping model. 2F-HAT5 exhibits a mobility of approximately 2x10$^{-3}$ cm$^{2}$/Vs, similar to the parent triphenylene, and has a weak temperature dependence throughout it's discotic mesophase, which extends below room temperature. We compare results on this and related compounds to various theoretical models.

Authors

  • Mitchell Powers

    • Kent State University
  • Zhe Li

    • Kent State University
  • Robert Twieg

    • Kent State University
  • Brett Ellman

    • Kent State University