Electrical conductivity of graphite oxide nanoplatelets obtained from bamboo: Effect of the deoxidation degree.

ORAL

Abstract

Given the high interest in the fabrication and application of carbon-based materials, we present a new and cost-effective method for the synthesis of graphite oxide nanoplatelets (GONP) using bamboo pyroligneous acid (BPA) as source. GONP-BPA present lateral dimensions of 5-100 micro-meter and thickness less than 80 nm, as confirmed by TEM. EEL spectra show that locally the carbon is mainly in sp$^{\mathrm{2}}$ bonding configuration and confirm a short/medium range crystalline order. Elemental analysis by EDX confirms the presence of oxygen in an atomic percentage ranging from 17 to 5{\%}. For electrical characterization, single platelets were contacted by focused-ion-beam-induced deposition of Pt nanowires. The four-point probe electrical conductivity shows a direct correlation with the oxygen percentage. Three orders of magnitude conductivity rise is observed by the oxygen reduction, reaching a value of 2.3x10$^{\mathrm{3}}$ S/m at the final deoxidation degree. The results suggest that GONP-BPA could be used in the development of advanced devices and sensors.

Authors

  • K. Gross

    • CENM of the Universidad del Valle
    • CENM, Universidad del Valle, Cali, Colombia
  • J. J. Prias-Barragan

    • IS Institute and Electronic IT Program of the Universidad del Quindio
    • IS Institute and Electronic IT Program, Universidad del Quindio, Armenia, Colombia
  • S. Sangiao

    • LMA, INA and DFMC, Universidad de Zaragoza, 50009 Zaragoza, Spain
  • J. M. De Teresa

    • DFMC and ICMA, CSIC, Universidad de Zaragoza, 50009 Zaragoza, Spain
  • L. Lajaunie

    • LMA, Instituto de Nanociencia de Aragon (INA), Universidad de Zaragoza, Spain
  • R. Arenal

    • LMA, Instituto de Nanociencia de Aragon (INA), Universidad de Zaragoza, Spain
  • H. Ariza-Calderón

    • CENM of the Universidad del Valle, Colombia
    • IS Institute, Universidad del Quindio, Armenia, Colombia
  • P. Prieto

    • Univ del Valle Cali
    • CENM, Universidad del Valle, Cali, Colombia