The ultrafast response of polar vortices under optical excitation

ORAL

Abstract

Polar vortices were recently discovered in PbTiO$_{\mathrm{3}}$-SrTiO$_{\mathrm{3}}$ superlattices [1], stabilized at the nanoscale in the presence of depolarizing fields and mechanical stresses. We have found that these exotic structures, non-existent in the bulk ferroelectrics, possess rich ultrafast responses to fs laser excitation, which is attractive for high-density information storage and nanoscale actuation. Using optical pulse excitation above the bandgap of PbTiO$_{\mathrm{3}}$ layers and structural and second harmonic generation probes of ferroelectric order dynamics, a series of reversible and irreversible nano-ordering transitions were observed. X-ray diffraction and diffuse scattering on nanodomains aided the phase identification during time-resolved measurements. In this talk, we will discuss the dynamic interplay between collinear and toroidal ferroelectric domains aided by understanding from phase field modelling. [1] A.K. Yadav, R. Ramesh et el., "Observation of Polar Vortices in Oxide Superlattices", accepted, Nature (2015).

*DE-SC0012375, DE-AC02-06CH11357, U.S Department of Energy, Office of Science, Office of Basic Energy Sciences

Authors

  • Vladimir Stoica

    • Pennsylvania State University
  • Yakun Yuan

    • Pennsylvania State University
  • Zijian Hong

    • Materials Science and Engineering, Pennsylvania State University
  • Ajay Yadav

    • University of California, Berkeley
  • Anoop Damodaran

    • University of California, Berkeley
  • Yi Zhu

    • APS, Argonne National Laboratory
  • Hua Zhou

    • Argonne National Laboratory
    • APS, Argonne National Laboratory
  • Donald Walko

    • Argonne National Lab
    • Argonne National Laboratory
    • APS, Argonne National Laboratory
  • John Freeland

    • Advanced Photon Source, Argonne National Lab, Argonne, IL
    • Advanced Photon Source, Argonne National Laboratory
    • Argonne National Lab
    • Argonne National Laboratory
    • APS, Argonne National Laboratory
  • Xiaoyi Zhang

    • APS, Argonne National Laboratory
  • Haidan Wen

    • Argonne National Lab
    • APS, Argonne National Laboratory
  • Long-Qing Chen

    • Pennsylvania State University
  • Ramamoorthy Ramesh

    • University of California Berkeley
    • University of California, Berkeley
  • Venkatraman Gopalan

    • Pennsylvania State University