Structure and magnetic ground states of spin-orbit coupled compound alpha-RuCl3

ORAL

Abstract

The layered material alpha-RuCl3 is composed of stacks of weakly coupled honeycomb lattices of octahedrally coordinated Ru3$+$ ions.~ The Ru ion ground state has 5 d electrons in the low spin state, with spin-orbit coupling very strong compared to other terms in the single ion Hamiltonian.~ The material is therefore an excellent candidate for investigating possible Heisenberg-Kitaev physics.~ In addition, this compound is very amenable to investigation by neutron scattering to explore the magnetic ground state and excitations in detail.~~In this talk, we discuss the synthesis of phase-pure alpha-RuCl3 and the characterization of the magnetization, susceptibility, and heat-capacity. We also report neutron diffraction on both powder and single crystal alpha-RuCl3, identifying the low temperature magnetic order observed in the material.~ The results, when compared to theoretical calculations, shed light on the relative importance of Kitaev and Heisenberg terms in the Hamiltonian.

*The research is supported by the DOE BES Scientific User Facility Division

Authors

  • Arnab Banerjee

    • Quantum Condensed Matter Division, ORNL, USA
  • Craig Bridges

    • Chemical Sciences Division, ORNL, USA
    • CSD, Oak Ridge National Laboratory
  • Jiaqiang Yan

    • Material Sciences Division, ORNL, USA
    • MSTD, Oak Ridge National Laboratory
    • Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
  • David Mandrus

    • Department of Physics, University of Tennessee, Knoxville, USA
    • Dep. of Mat. Sci. and Eng., U. Tennessee
    • Oak Ridge National Laboratory / Univ of Tennessee
    • Department of Materials Science \& Engineering, University of Tennessee, Knoxville
  • Matthew Stone

    • Quantum Condensed Matter Division, ORNL
    • Oak Ridge National Laboratory
    • Quantum Condensed Matter Division, ORNL, USA
    • QCMD, Oak Ridge National Laboratory
    • Oak Ridge National Lab
  • Adam Aczel

    • Quantum Condensed Matter Division, ORNL
    • Quantum Condensed Matter Division, ORNL, USA
    • QCMD, Oak Ridge National Laboratory
    • Oak Ridge National Laboratory
    • Quantum Condensed Matter Division, Oak Ridge National Laboratory
  • Ling Li

    • Department of Physics, University of Tennessee, Knoxville, USA
  • Yuen Yiu

    • Department of Physics, University of Tennessee, Knoxville, USA
    • Dep. of Physics, U. Tennessee
  • Mark Lumsden

    • Quantum Condensed Matter Division, ORNL, USA
    • QCMD, Oak Ridge National Laboratory
    • Oak Ridge National Lab
  • Bryan Chakoumakos

    • Quantum Condensed Matter Division, ORNL, USA
  • Alan Tennant

    • Neutron Sciences Directorate, ORNL, USA
    • NScD, Oak Ridge National Laboratory
    • Oak Ridge National Laboratory
    • Oak Ridge National Laboratory, Oak Ridge, TN, USA
  • Stephen Nagler

    • Quantum Condensed Matter Division, ORNL, USA
    • QCMD, Oak Ridge National Laboratory