Charge Transport and Structural Dynamics in Deep Eutectic Mixtures

POSTER

Abstract

Charge transport and structural dynamics in a series of imidazole and carboxylic acid-based deep eutectic mixtures are investigated by broadband dielectric spectroscopy, dynamic light scattering, $^{1}$H nuclear magnetic resonance spectroscopy, calorimetry, and Fourier transform infrared spectroscopy. It is found that the extended hydrogen-bonded networks characteristic of imidazoles are broken down upon addition of carboxylic acids, resulting in an increase in dc conductivity of the mixtures. These results are discussed within the framework of recent theories of hydrogen bonding and proton transport.

Authors

  • Tyler Cosby

    • University of Tennessee, Knoxville

  • Adam P. Holt

    • University of Tennessee, Knoxville
    • Department of Physics and Astronomy, University of Tennessee, Knoxville
    • Department of Physics, University of Tennessee

  • Logan Terheggen

    • University of Tennessee, Knoxville
    • Univ of Tennessee, Knoxville

  • Philip Griffin

    • University of Pennsylvania
    • Department of Materials Science and Engineering, University of Pennsylvania

  • Roberto Benson

    • University of Tennessee, Knoxville

  • Joshua Sangoro

    • University of Tennessee, Knoxville
    • Univ of Tennessee, Knoxville
    • Department of Physics and Astronomy, University of Tennessee