Flow mechanism of colloidal solutions under shear revealed by neutron scattering and simulation

ORAL

Abstract

Using small angle neutron scattering technique and Brownian dynamics simulation we investigate the effect of external steady shear on the concentrated solutions of silica particles in the shear thinning region. Three dimensional anisotropic structure factors are obtained as a function of shear rate. Accordingly the evolution of local topology, defined by the colloidal connectivity, is revealed by the variation of local strain. We further determine the elastic responsive length scale of the colloidal systems via characterizing the quantitative dependence of the correlation length on the strain rate.

*Research presented in this work is supported by the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Energy Division.

Authors

  • Xin Li

    • Oak Ridge National Laboratory
  • Wei-Ren Chen

    • Oak Ridge National Lab
    • Oak Ridge National Laboratory
  • Luis Sanchez-Diaz

    • Oak Ridge National Lab
    • Oak Ridge National Laboratory
  • Yun Liu

    • National Institute of Standards and Technology
  • Lionel Porcar

    • Institut Laue-Langevin, Grenoble, France
    • Institut Laue-Langevin
  • William Hamilton

    • Oak Ridge National Laboratory
  • Changwoo Do

    • Oak Ridge National Laboratory
  • Takuya Iwashita

    • University of Tennessee
    • Univ of Tennessee, Knoxville
  • Egami Takeshi

    • Univ of Tennessee - Knoxville
    • University of Tennessee
    • Univ of Tennessee, Knoxville
  • Kao-Hsiang Liu

    • University of Tennessee