Photo-induced dynamics of charge ordering in La$_{1/3}$Sr$_{2/3}$FeO$_{3}$ probed by ultrafast hard x-ray diffraction

ORAL

Abstract

La$_{1/3}$Sr$_{2/3}$FeO$_{3}$ thin films exhibit strong charge ordering due to charge disproportionation of Fe$^{3+}$/Fe$^{5+}$ ions along the [111] direction below T$_{c}$ $\sim$ 200K. In this study, a La$_{1/3}$Sr$_{2/3}$FeO$_{3}$ thin film was excited by ultrafast 355nm laser pulses, and the response of the charge ordering and the lattice was directly observed via ultrafast hard x-ray diffraction. We identified the threshold of the excitation laser fluence to melt the charge ordering diffraction peak. We also found charge ordering recovers in a few nanoseconds, faster than the lattice recovery. These findings indicate the non-thermal nature of the photo-induced dynamics of charge disordering in La$_{1/3}$Sr$_{2/3}$FeO$_{3}$.

*Work at Argonne was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357

Authors

  • Yi Zhu

    • Advanced Photon Source, Argonne National Lab
    • Argonne National Lab
  • Jason Hoffman

    • Center for Nanoscale Materials, Argonne National Laboratory
    • Argonne National Laboratory
  • Clare Rowland

    • Center for Nanoscale Materials, Argonne National Laboratory
  • D.A. Walko

    • Advanced Photon Source, Argonne National Lab
    • Argonne National Lab
  • John Freeland

    • Advanced Photon Source, Argonne National Lab
    • Argonne National Laboratory
  • Phillip Ryan

    • Advanced Photon Source, Argonne National Lab
    • Argonne National Laboratory
  • Richard Schaller

    • Center for Nanoscale Materials, Argonne National Laboratory
  • Anand Bhattacharya

    • Center for Nanoscale Materials, Argonne National Laboratory
    • Argonne National Laboratory
    • MSD and NST, Argonne National Laboratory
  • Haidan Wen

    • Advanced Photon Source, Argonne National Lab
    • Argonne National Lab