Physical properties of Rh substituted CaFe$_{2}$As $_{2}$ tuned by annealing/quenching
ORAL
Abstract
Our previous work on CaFe$_{2}$As$_{2}$ single crystal grown out of FeAs flux has shown that a process of annealing and quenching can be used as an additional control parameter which can tune the ground state of CaFe$_{2}$As$_{2}$ systematically. We have also shown that CaFe$_{2}$As$_{2}$ is very pressure sensitive. Therefore, unlike the BaFe$_{2}$As$_{2}$ system, the effect of 4d transition metal substitution on CaFe$_{2}$As$_{2}$ is expected to be largely different from that of 3d transition metal substitution (e.g. cobalt or nickel substitution). In this talk we will present results of measurements on a Rh substituted CaFe$_{2}$As$_{2}$ system with different annealing/quenching temperatures. Phase diagrams with substitution level and annealing/quenching temperature as independent parameters are constructed and compared with that of other transition metal substitutions.
*Supported by the U.S. Department of Energy Basic Energy Sciences under Contract No. DE-AC02-07CH11358
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