Phonons in solid picene at high pressures

ORAL

Abstract

Intercalated hydrocarbons have attracted considerable interest as a new class of superconductors. Calculations of the $e-ph$ interaction in different approximations yield conflicting results on the role of inter and intra-molecular vibrations in the pairing. We present an experimental and theoretical study of the phonon spectrum of solid picene under high pressure. We introduce a new theoretical analysics, based on the projection of phonon eigenvectors, to quantify the increase of intermolecular character under pressure. F. Capitani et al., Phys. Rev. B 88, 144303 (2013).

Authors

  • Lilia Boeri

    • Technical University Graz
    • TU-Graz
  • F. Capitani

    • Dipartimento di Fisica, Universit\`a di Roma Sapienza, Italy
  • M. Hoeppner

    • Max-Planck-Institute for Solid State Research, Stuttgart, Germany
  • B. Joseph

    • Dipartimento di Fisica, Universit\`a di Roma Sapienza, Italy
  • G.A. Artioli

    • Dipartimento di Chimica, Universit\`a di Pavia, Italy
  • L. Baldassarre

    • Center for Life NanoScience@Sapienza, IIT, Roma, Italy
  • A. Perucchi

    • Sincrotrone Trieste, S.C.p.A., Area Science Park, Trieste, Italy
  • M. Piccinini

    • Porto Conte Ricerche S.r.l., Alghero (SS), Italy
  • S. Lupi

    • CNR-IOM and Dipartimento di Fisica, Universit\`a di Roma Sapienza, Italy
  • P. Dore

    • CNR-SPIN and Dipartimento di Fisica, Universit\`a di Roma Sapienza, Italy
  • L. Malavasi

    • Dipartimento di Chimica, Universit\`a di Pavia, Italy
  • P. Postorino

    • Dipartimento di Fisica, Universit\`a di Roma Sapienza, Italy