Ultrasound Velocity Measurements in the Orbital-Degenerate Frustrated Spinel MgV$_2$O$_4$

ORAL

Abstract

Magnesium vanadate spinel MgV$_2$O$_4$ is a geometrically frustrated magnet with $t_{2g}$-orbital degeneracy of V$^{3+}$ (3$d^2$), which undergoes a cubic-to-tetragonal structural transition at $T_s$ = 65 K and an antiferromagnetic (AF) transition at $T_N$ = 42 K. For MgV$_2$O$_4$, it is considered that the occurrence of $t_{2g}$-orbital order at $T_s$ causes the release of frustration by the AF ordering at $T_N$ lower than $T_s$. We performed ultrasound velocity measurements in high-purity single crystal of MgV$_2$O$_4$. Temperature dependence of the tetragonal shear modulus ($C_{11}-C_{12}$)/2 exhibits huge Curie-type softening in the cubic paramagnetic (PM) phase ($T>T_s$), which should be a precursor to the cubic-to-tetragonal lattice distortion at $T_s$. The trigonal shear modulus $C_{44}(T)$ exhibits softening with an upturn curvature in the cubic PM phase, indicating a coupling of the lattice to magnetic excitations. These softenings suggest the coexistence of the dynamical Jahn-Teller effect and the dynamical magnetic state in the cubic PM phase.

Authors

  • Tadataka Watanabe

    • Department of Physics, College of Science and Technology (CST), Nihon University, Chiyoda, Tokyo 101-8308, Japan
  • Takashi Ishikawa

    • Department of Physics, College of Science and Technology (CST), Nihon University, Chiyoda, Tokyo 101-8308, Japan
  • Shigeo Hara

    • Department of Physics, Chuo University, Bunkyo, Tokyo 101-8324, Japan
  • A.T.M. Nazmul Islam

    • Helmholtz Zentrum Berlin, GmbH, D-14109 Berlin, Germany
  • Elisa M. Wheeler

    • Helmholtz Zentrum Berlin, GmbH, D-14109 Berlin, Germany
  • Bella Lake

    • Helmholtz Zentrum Berlin, GmbH, D-14109 Berlin, Germany