Coherent States Formulation of Polymer Field Theory

ORAL

Abstract

We introduce a stable and efficient complex Langevin scheme to enable the first direct numerical simulations of the coheret-states (CS) formulation of polymer field theory. In contrast with Edwards' well known auxiliary-field framework, the CS formulation does not contain an embedded nonlinear, non-local, implicit functional of the auxiliary fields and the action of the field theory has a fully explicit, semi-local and finite-order polynomial character. We present the route for deriving CS canonical ensemble theories, and a method for studying asymptotically long polymer chains with composition fluctuations fully included using a simplified field theory in the ground-state-dominance approximation. The formalism is potentially applicable for conducting systematic coarse-graining and numerical renormalization-group studies

*This work is supported by the NSF under award DMR-CMMT-1160895 and the SOLAR program award No. CHE-1035292. This work was partially supported by the MRSEC program of the NSF No. DMR-1121053. Computational resourses were supported by NSF CNS-0960316.

Authors

  • Xingkun Man

    • BUAA
  • Kris Delaney

    • UCSB
  • Michael Villet

    • UCSB
  • Henri Orland

    • ITP
  • Glenn Fredrickson

    • UCSB