Combined effects of annealing/quenching and transition metal substitution on physical properties of CaFe$_{2}$As$_{2}$
ORAL
Abstract
Our previous work on CaFe$_{2}$As$_{2}$ single crystals grown out of FeAs flux has shown that a process of annealing and quenching can be used as an additional control parameter which can tune the ground state of CaFe$_{2}$As$_{2}$ systematically, in a manner similar to applied pressure. With combined effect of annealing/quenching and transition metal substitution, CaFe$_{2}$As$_{2}$ system offers ready access to the salient low-temperature states associated with Fe-based superconductors: antiferromagnetic/orthorhombic, superconducting, and nonmagnetic/collapsed tetragonal. In this talk we will present systematic studies of the combined effects of annealing/quenching and chemical substitution with various transition metals (Co, Ni, Rh) on the physical properties of CaFe$_{2}$As$_{2}$ and construct phase diagrams for different substitution levels and different annealing/quenching temperatures.
*Supported by the U.S. Department of Energy Basic Energy Sciences under Contract No. DE-AC02-07CH11358.
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