Transparent oxide semiconductors (Ba,La)SnO$_{3}$ with high mobility at room temperature

ORAL

Abstract

We present our discovery of (Ba,La)SnO$_{3}$ system exhibiting electrical mobility at 300 K of 200-320 cm$^{2}$V$^{-1}$s$^{-1}$ in a doping range from 1.0x10$^{19}$ to 4.0x10$^{20}$ cm$^{-3}$. Moreover, their conductivity values were as large as around 10$^{4}$ S/cm, being comparable to those of indium tin oxides. The system yet shows the optical gap around 3.33 eV and only slight increase of the in-gap states, maintaining visual transparency. Several unique physical properties of (Ba,La)SnO$_{3}$ are also discussed: a superior oxygen stability evidenced by persistent transport properties under high temperature environments, a small effective mass coming from the ideal Sn-O-Sn bonding in a cubic perovskite, small disorder effects due to doping away from the main conduction channels (SnO$_{6}$ octahedra network) and reduced carrier scattering due to the high dielectric constant. (Ba,La)SnO$_{3}$ thus holds great potential for realizing transparent, high power, high temperature functional devices.

Authors

  • Hyung Joon Kim

    • Department of Physics and Astronomy, Seoul National University
  • Useong Kim

    • Department of Physics and Astronomy, Seoul National University
  • Tai Hoon Kim

    • Department of Physics and Astronomy, Seoul National University
  • Jiyeon Kim

    • Department of Physics and Astronomy, Seoul National University
  • Hoon Min Kim

    • Department of Physics and Astronomy, Seoul National University
  • Byung-Gu Jeon

    • Department of Physics and Astronomy, Seoul National University
  • Woong-Jhae Lee

    • Department of Physics and Astronomy, Seoul National University
  • Hyo Sik Mun

    • Seoul National University
  • Kwang Taek Hong

    • Department of Physics and Astronomy, Seoul National University
  • Jaejun Yu

    • Department of Physics and Astronomy, Seoul National University
  • Kookrin Char

    • Department of Physics and Astronomy, Seoul National University
  • Kee Hoon Kim

    • Department of Physics and Astronomy, Seoul National University