Accelerated discovery of materials for solar fuel cells at JCAP

ORAL

Abstract

High-Throughput Experimentation group at the Joint Center for Artificial Photosynthesis has a formidable mission: provide accelerated discovery of new photon absorbers and heterogeneous (photo)catalysts for solar fuel cells at the rate far beyond anything attempted in material science to date. The HTE pipeline includes material synthesis, screening and characterization. Within the first year of operations, our fabrication capabilities have risen to 100,000 samples per day using combinatorial inkjet-printing. Such high rate of sample production is setting daunting requirements on screening methods. We are developing and testing methods for fast bandgap measurements, using colorimetry and uv-vis spectroscopy. Material thickness and roughness is determined by confocal chromatic spectroscopy. Catalytic activity is screen through a massively parallel bubble screen and a fast scanning droplet (photo)electrochemical cell. Concurrently, we are developing protocols for high-throughput determination of phase and structure (XRD), surface composition and chemistry (XPS), surface area measurement, etc. on the characterization side of the pipeline.

*This work was performed at Joint Center for Artificial Photosynthesis, a DOE Energy Innovation Hub, supported through the Office of Science of the U.S. Department of Energy under Award No. DE-SC0004993

Authors

  • Slobodan Mitrovic

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Earl Cornell

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • John Gregoire

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Joel Haber

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Kevin Kan

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Sean Lin

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Xiaonao Liu

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Martin Marcin

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Edward Soedarmadji

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Santosh Suram

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Chengxiang Xiang

    • Joint Center for Artificial Photosynthesis, California Institute of Technology
  • Jian Jin

    • Joint Center for Artificial Photosynthesis, California Institute of Technology