Long-range plasmon-assisted energy transfer over doped graphene
ORAL
Abstract
F\"orster resonance energy transfer (FRET) between spatially separated donor and acceptor fluorophores, such as dye molecules or semiconductors quantum dots, underpins diverse phenomena in physics, chemistry and biology. However, the range of present and potential applications of FRET is limited by its intrinsically short-range nature ($\sim 1/R^6$). We demonstrate that longitudinal plasmons in doped monolayer graphene can mediate highly efficient long-range ($\sim 1/R$) energy transfer between nearby fluorophores, e.g., semiconductor quantum dots. We derive a simple analytical expression for the energy transfer efficiency that incorporates all the essential processes involved. We perform numerical calculations of the transfer efficiency for a pair of PbSe quantum dots near graphene for inter-fluorophore distances of up to 1 $\mu$m and find that the plasmon-assisted long-range energy transfer can be enhanced by up to a factor of $\sim 10^4$ relative to FRET in vacuum.
*Work at LANL was performed under the NNSA of the U.S. DOE at LANL under Contract No. DE-AC52- 06NA25396. Work at JSU was supported by the NSF under Grants No. DMR-1206975 and No. HRD-0833178 and under EPSCOR program.
–