Correction of Doi-Edwards' Green function in harmonic potential and its implication for stress-optical rule
ORAL
Abstract
We derive a corrected Green's function for a polymer chain trapped in a two-dimensional anisotropic harmonic potential with a fixed boundary condition. This Green's function is a modified version of what Doi and Edwards first derived to describe the polymer chain trapped in the tube-like domain of surrounding entangled polymers [J. Chem. Soc. Farad. Trans. II 74 (1978) 1802]. In contradiction to the results found by Ianniruberto and Marrucci using the incorrect Green's function [J. Non-Newtonian Fluid Mech. 79 (1998) 225], we find that the stress-optical rule is violated for any tube potential either circular or elliptic. The violation is due to the presence of the virtual springs to trap the chain in the tube rather than the anisotropy of the confinement potential.
*Army Research Office (grants W911NF-08-2-0058 and W911NF-09-1-0378)
–