Inter-chain transport in the quasi-one-dimensional metal, Li$_{0.9}$Mo$_6$O$_{17}$

ORAL

Abstract

We report measurements of electrical resistivity ($\rho$) and thermoelectric power ($S$) transverse to the conducting chains (crystallographic \textit{c} axis) on single crystals of the quasi-one-dimensional metal, Li$_{0.9}$Mo$_6$O$_{17}$. While $\rho_c(T)$ exhibits metallic behavior at $T\leq T_{max}\sim 270$~K, it decreases with increasing $T$ above this temperature similar to the behavior of $\rho$ transverse to the conducting planes in a variety of two-dimensional metals.\footnote{See, e.g., D. B. Gutman and D. L. Maslov, Phys. Rev. Lett. {\bf 99}, 196602 (2007).} We discuss the corresponding thermopower, $S_c$, which is relatively $T$-independent and a modest 30 $\mu$V/K at low $T$, increases sharply with increasing $T$ near $T_{max}$, and exceeds 200 $\mu$V/K at $T>400$~K.

*Work supported by the U.S. Department of Energy Office of Basic Energy Sciences (DE-FG02-12ER46888, Univ.~Miami), the National Science Foundation (DMR-0907036, Mont.~St.~Univ.), and in Lorena by the CNPq (301334/2007-2) and FAPESP (2009/14524-6).

Authors

  • Joshua Cohn

    • University of Miami
  • Benjamin D. White

    • Montana State University
  • Carlos A.M. dos Santos

    • Escola de Engenharia de Lorena - USP, Brazil
  • John J. Neumeier

    • Montana State University