Coupled oscillations in a 1D emulsion of Belousov--Zhabotinsky droplets

ORAL

Abstract

We experimentally and computationally study the dynamics of interacting oscillating Belousov--Zhabotinsky (BZ) droplets of 100 micron diameter separated by perfluorinated oil and arranged in a one-dimensional array. A microfluidic chip is used for mixing the BZ reactants, forming monodisperse droplets by flow-focusing and directing them into a hydrophobized 100 micron diameter capillary. In order to make quantitative comparison with theory, we use photosensitive Ru(bipy)$_{3}$ catalyzed BZ droplets and set both boundary and initial conditions of arrays of small numbers of oscillating BZ droplets with a programmable illumination source. The coupling strength is a function of malonic acid concentration and varying coupling strength leads to the generation of different dynamical attractors. In many cases, simulations agree well with experiments.

*Funded by MRSEC.

Authors

  • Ning Li

    • Brandeis University
  • Jorge Delgado

    • University of Guanajuato
  • Hector Gonzalez Ochoa

    • San Luis Potosi Institute of Scientific Research and Technology (IPICyT)
  • Marcin Leda

    • Institute of Physical Chemistry (Polish Academy of Science)
  • Seth Fraden

    • Brandeis University
  • Irving Epstein

    • Brandeis University