Combined surface plasmon resonance and X-ray absorption spectroscopy
ORAL
Abstract
We present a system for the excitation and measurement of surface plasmons in metallic films based on the Kretschmann-Raether configuration that can be installed in a synchrotron beamline. The device was mounted an tested in a hard X-ray Absorption beamline, BM25 Spline at ESRF. Whit this device it is possible to carry on experiments combining surface plasmon and X-ray absorption spectroscopies. The surface plasmons can be use to monitor in situ changes induced by the X-rays in the metallic films or the dielectric overlayer. Similarly, the changes in the electronic configuration of the material when surface plasmons are excited can be measured by X-ray absorption spectroscopy. The resolution of the system allows to observe changes in the signals of the order of 10$^{-3}$ to 10$^{-5}$ depending on the particular experiment and used configuration. The system is available for experiments at the beamline.
*This work was supported by the Spanish Ministry of Science and Education through the project FIS-2008-06249. We acknowledge the ESRF for provision of synchrotron radiation facilities and the SpLine beamline staff for assistance during XAS experiments.
–